Articles
Zui O.V. Development of ion chromatography in Ukraine
UDC: 543.544.6:543.3
DOI: 10.15407/zht2021.67.039
Zui O.V.
Development of ion chromatography in Ukraine
The ways of development of ion chromatography in Ukraine from the eighties of the last century to the present time are shown. The achievements of research institutes, in particular, the Dumansky Institute of Colloid Chemistry and Water Chemistry of the National Academy of Sciences of Ukraine, in the development of ion chromatographic methods for the analysis of organic and inorganic anions in various objects, including natural and drinking waters, are highlighted. Scientists of Ukraine (A.T. Pilipenko, O.V. Zuy, A.V. Terletskaya) compared commercially available sorbents for ion chromatography – HIKS-1, ANIEKS-N and KANK ASt for their use in water analysis. The studies were carried out on an ion chromatograph "Tsvet-3006" with a conductometric detector. It has been shown that ANIEKS-N with a borate eluent is the best sorbent for the determination of organic monocarboxylic acid ions, and KANK ASt with a carbonate-hydrocarbonate eluent – for the determination of inorganic anions. Ion chromatography has been used to solve a number of practical problems: for the separation of oxoanions iodate, chlorate and bromate in waters, to control the results in the development of chemiluminescent methods for the determination of chloride, nitrite and nitrate, to establish the mechanism of destruction of anionic surfactants under the action of vacuum ultraviolet radiation and corona discharge. The method was applied to the analysis of iodine-containing bottled waters for bromide ions due to the absence of the interference from iodides. The accumulated experience has contributed to the adoption in Ukraine of four state standards for water quality, based on the use of the ion chromatographic method. It is shown that the method of ion chromatography at the present stage is widely used in various sectors of the national economy: to determine the traces of anions in steam condensate of power plants, to control the anionic composition of water at nuclear power plants, to correct water treatment processes at waterworks, in particular, when analyzing chlorite ions in tap water obtained with the use of chlorine dioxide as a disinfectant.
Keywords: ion chromatography, sorbents, eluents, organic anions, inorganic anions.
REFERENCES
1. Small H., Stevens T.S., Bauman W.C. Novel ion exchange chromatographic method using conductimetric detection. Anal. Chem. 1975. Vol. 47. No 11. P. 1801-1809.
2. Shpigun O.A., Zolotov Yu.A. Ion chromatography – method of rapid and selective determination of ions. Zavodskaya Laboratoriya. 1982, 48(9), P. 4-14.
3. Shpigun O.A., Zolotov Yu.A. Ion chromatography in water analysis. Chichester: Ellis Horwood, 1988. 188 p.
4. Lukachina V.V., Terletskaya A.V., Bogoslovskaya T.A., Zuy O.V., Kofanov V.I., Shevchenko T.L., Yurchenko V.V., Matsibura G.S. Methodological support of a mobile laboratory for the determination of harmful contaminants of natural and drinking water. Khimiya i Tekhnologiya Vody. 1994, 16(4), P. 451-455.
5. Pilipenko A.T., Zuy O.V., Terletskaya A.V. Ion chromatographic determination of anions in waters using central- and surface-modified sorbents. Khimiya i Tekhnologiya Vody. 1992, 14(11), P. 819-825.
6. Lozovskii A.V., Stolyarova I.V., Prikhod’ko R.V., Goncharuk V.V. Research of photocatalytic activity of the Ag/TiO2 catalysts in the reduction reaction of nitrate–ions in aqueous media. Journal of Water Chemistry and Technology. 2009, 31(6), P. 360-366. DOI: https://doi.org/10.3103/S1063455X09060034
7. Mazna Yu.I., Zuy O.V. Ion chromatographic determination of bromides in iodinated waters. Kyiv Conference on Analytical Chemistry “Modern Trends 2017”. Book of Abstracts. Kyiv: Taras Shevchenko University, 2017. P. 97.
8. Zui O.V. Chemiluminescence method for the determination of chloride in waters using dynamic gas extraction of chlorine. Fresenius’ J. Anal. Chem. 1995. Vol. 351, No 2-3. P. 209-211. doi: https://doi.org/10.1007/BF00321639
9. Zui O.V., Terletskaya A.V. Rapid chemiluminescence method for the determination of iodate traces. Fresenius’ J. Anal. Chem. 1995. Vol. 351, No 2-3. P. 212-215. DOI: https://doi.org/10.1007/BF00321640
10. Mamaenko A.V., Dolenko S.A., Zuy O.V., Prikhod’ko R.V., Goncharuk V.V. Application of ion chromatography for establishing the mechanism of anionic surfactants destruction by vacuum UV irradiation and corona discharge. East European Scientific Journal (Warsaw, Poland). 2019, 41(1), P. 46-52.
11. Pilipenko A.T., Bolshak Yu.V., Zuy O.V., Manilevich T.M. Determination of nitrates in waters by ion chromatographic and ionometric methods. Khimiya i Tekhnologiya Vody. 1991, 13(10), P. 904-908.
12. Zuy O.V., Terletskaya A.V., Falendysh E.R., Drapailo O.M. Rational methods for anion determination in waters. Khimiya i Tekhnologiya Vody. 1994, 16(4), P. 444-450.
13. DSTU ISO 10304-1:2003. Water Quality. Determination of dissolved fluoride, chloride, nitrite, orthophosphate, bromide, nitrate and sulphate ions by liquid chromatography method. Part 1. Metod for slightly polluted waters. Kyiv: Derzhspozhyvstandart Ukrainy, 2004. 14 p.
14. DSTU ISO 10304-2:2003. Water Quality. Determination of dissolved anions by ion chromatography method. Part 2. Determination of bromide, chloride, nitrate, nitrite, orthophosphate and sulphate in wastewater. Kyiv: Derzhspozhyvstandart Ukrainy, 2004. 15 p.
15. DSTU ISO 10304-3:2003. Water Quality. Determination of dissolved anions by ion chromatography method. Part 3. Determination of chromate, iodide, sulphite, thiocyanate and thiosulphate. Kyiv: Derzhspozhyvstandart Ukrainy, 2005. 18 p.
16. DSTU ISO 10304-4:2003. Water Quality. Determination of dissolved anions by ion chromatography method. Part 4. Determination of chlorate, chloride and chlorite in slightly polluted water. Kyiv: Derzhspozhyvstandart Ukrainy, 2005. 13 p.
17. DSanPiN Ukrainy 2.2.4-171-10. Hygienic requirements for drinking water intended for human consumption. Approved by the order of the Ministry of Health of Ukraine dated 12.05.2010 for N 400.