Articles

Baranov Yu.S., Demchenko V.F., Zajets Ie.R., Olszewski S.V. Herbicides from the group of nitrodiphenyl ethers: applications in Ukraine, control methods, methods for determination of oxifluorphene residues in soybean grain and oil

UDC:613:632.95.028:633.491
DOI: 10.15407/zht2020.66.015

Baranov Yu.S., Demchenko V.F., Zajets Ie.R., Olszewski S.V.

Herbicides from the group of nitrodiphenyl ethers: applications in Ukraine, control methods, methods for determination of oxifluorphene residues in soybean grain and oil

A review of analytical methods for the determination of herbicide residues from the group of nitrodiphenyl ethers in the environment and agricultural products, developed and validated a method for oxyfluorfen determination in soybean grain and oil method GC/ECD, which meets regulatory requirements and solves the problem of toxicant control in the above matrices. The developed method uses modern methods of sample preparation, identification and quantification of oxyfluorfen (selective extraction, capillary gas-liquid chromatography (GC/ECD GC/MS). The method is validated according to EU requirements) (SANTE/12682/2019 quality control and analytical validation procedures for pesticide residues analysis in food and feed).
Key words: gas-liquid chromatography, mass spectrometry, herbicides, nitrodiphenyl ethers, control, residual amounts.

REFERENCES

1. List of pesticides and agrochemicals that are allowed for use in Ukraine // Ministry of Ecology and Natural Resources of Ukraine DOI: https://mepr.gov.ua/content/derzhavniy-reestr-pesticidiv-i-agrohimikativ-dozvolenih-do-vikoristannya-v-ukraini-dopovnennya-z-01012017-zgidno-vimog-postanovi-kabinetu-ministriv-ukraini-vid-21112007--1328.html
2. IUPAC The PPDB Pesticide Properties Database. DOI: http://sitem.herts.ac.uk/aeru/iupac/
3. Guidelines for the determination of goal in water, soil and plant objects by thin-layer chromatography. Methods for the determination of trace amounts of pesticides in food, feed and the environment: Handbook. - Vol. 1 / Ed. by Klisenko M.A. et al. M.: Kolos, 1992. P. 229-232 DOI: https://standartgost.ru/g/%D0%9C%D0%A3_3063-84
4. Kofman I.Sh., Kofanov V.I. Thin-layer chromatography of diphenyl ether herbicides in combination with spectrodensitometry. Journal of Analytical Chemistry. 1987, Vol. XLII (no. 12), S. 2241-2244.
5. Shobha Sondhia, Anil Dixit. Determination of Terminal Residues of Oxyfluorfen in Onion. Ann. Pl. Protec. Sci. March, 2007, 15 (1), R. 232-234 DOI: https://www.researchgate.net/publication/280941299_Determination_of_terminal_residues_of_oxyfluorfen_in_onion
6. Ajoy Saha, Ahammed Shabeer TP, Kaushik Banerjee, Sandip Hingmire, Debarati Bhaduri, NK Jain, Sagar Utture. Simultaneous analysis of herbicides pendimethalin, oxyfluorfen, imazethapyr and quizalofop-p-p-safety by LC-MS/MS and evaluation harvest time residues in peanut (Arachis hypogaea L.). J. Food Sci. Technol. 2015 Jul, 52(7), P. 4001-4014. DOI: 10.1007/s13197-014-1473-9
7. Khansaa Fatta Alrahman, Abdala A Elbashir, Hassan El-obid Ahmed Development Validation of Spectrophotometric Method for Determination of Oxyfluorfen Herbicide Residues. Med chem. 2015, 5, 8. P. 383-388. DOI: 10.4172/2161-0444.1000290
8. Guidelines for the determination of residual amounts of oxyfluorfen in sunflower seeds and oil by gas-liquid chromatography Determination of pesticides residues in food, agricultural raw materials and environmental objects. MUK 4.1.2056-06. M.: 1981. P. 91-100. DOI: https://files.stroyinf.ru/Index2/1/4293824/4293824279.htm
9. Zeying He, Lu Wang, Yi Peng, Ming Luo, Xiaowei Liu QuEChERS approach combined with an Agilent 7000 Series Triple Quadrupole GC / MS system to analyze the residuts content of more than 200 types of pesticides in cereals. Institute of Agriculture and Environmental Protection, Ministry of Agriculture of the People`s Republic of China. USA: Agilent Technologies, Inc., March 2, 2015. 10 pp. DOI: https://www.agilent.com/cs/library/applications/5991-5553EN.pdf
10. Baranov Yu.S. Khilik L.A., Brynza E.A. Determination of residual amounts of herbicidal diphenyl ethers in soil, plants and essential oils. Agrochemistry. 1985, vol. 7, P. 110-113.
11. Baranov Yu.S. Khilik L.A., Brynza E.A. Methodological guidelines for the determination of nitrochlor and preforan in essential oils and oil-containing raw materials by the method of gas-liquid chromatography. Methods for the determination of trace amounts of pesticides in food, feed and the environment. M.: 1981. Sb. 11, P. 8-14.
12. Baranov Yu.S. Khilik L.A., Brynza E.A. Guidelines for the determination of goal in soil, essential oil plants and essential oils by gas-liquid chromatography // Methods for the determination of trace amounts of pesticides in food, feed and the environment: Handbook. - Vol. 1 / Ed. by Klisenko M.A. et al. M.: Kolos, 1992. P. 232-235. DOI: https://files.stroyinf.ru/Data2/1/4293748/4293748751.pdf
13. Baranov Yu.S. Temporary guidelines for the determination of modaun in essential oils by gas-liquid chromatography. Methods for the determination of trace amounts of pesticides in food, feed and the environment. M.: 1995. Sb. 21, vol. 1. P. 168-173.
14. Main changes introduced in Document N SANTE/12682/2019 with respect to the previous version (Document N SANTE/11813/2017). 53 p. DOI: https://ec.europa.eu/food/sites/food/files/plant/docs/pesticides_mrl_guidelines_wrkdoc_2019-12682.pdf