Articles

MILYUKIN M.V., GORBAN M.V. MONITORING AND DISPERSE-PHASE DISTRIBUTION OF LIGHT POLYCYCLIC AROMATIC HYDROCARBONS IN NATURAL WATER

2016 – Zurnal Hromatografichnogo Tovarystva – V. XVI. – N 1-4. – P. 5-13

UDC [543.54+543.51:547.993]504.064.3:574.64

DOI: 10.15407 / zht2016.59.005

MILYUKIN M.V., GORBAN M.V.

A. V. Dumansky Institute of Colloid and Water Chemistry NAS of Ukraine, Kyiv

MONITORING AND DISPERSE-PHASE DISTRIBUTION OF LIGHT POLYCYCLIC AROMATIC HYDROCARBONS IN NATURAL WATER article

In the samples of natural water of Dnieper River, collected in Kiev region during the period between 2011 and 2013 years, concentrations of 10 light polycyclic aromatic hydrocarbons (PAHs) were determined and disperse-phase distribution of them was established. The total content of light PAHs (naphthalene, acenaphthylene, acenaphthene, fluorine, phenanthrene, anthracene, fluoranthene, pyrene, benz(a)anthracene, chrysene) ranged between 5.5 and 287.4 ng/dm³. Naphthalene, phenanthrene, fluoranthene prevailed in natural water of Dnieper River, their maximal concentrations were, respectively, 194.5, 142.5, 55.7 ng/l. Shares of light PAHs at rough and thin fractions of suspended particulate matter and their water-soluble part were on average 19, 39 and 42 % respectively. It was established, that disperse-phase distribution of individual PAHs depends on the number of aromatic rings in the molecule of the compound: the higher this number the lower water-soluble part of PAH. Only naphthalene exists predominantly in water-soluble state. PAHs with number of aromatic rings 3 or 4 are almost completely associated with suspended particles.

Keywords: natural water, Dnieper River, light PAHs, SPE, HPLC/FD, monitoring, disperse-phase distribution

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