Articles

MILYUKIN M.V., GORBAN M.V. MONITORING AND DISPERSE-PHASE DISTRIBUTION OF LIGHT POLYCYCLIC AROMATIC HYDROCARBONS IN NATURAL WATER

2016 – Zurnal Hromatografichnogo Tovarystva – V. XVI. – N 1-4. – P. 5-13

UDC [543.54+543.51:547.993]504.064.3:574.64

DOI: 10.15407 / zht2016.59.005

MILYUKIN M.V., GORBAN M.V.

A. V. Dumansky Institute of Colloid and Water Chemistry NAS of Ukraine, Kyiv

MONITORING AND DISPERSE-PHASE DISTRIBUTION OF LIGHT POLYCYCLIC AROMATIC HYDROCARBONS IN NATURAL WATER - article

In the samples of natural water of Dnieper River, collected in Kiev region during the period between 2011 and 2013 years, concentrations of 10 light polycyclic aromatic hydrocarbons (PAHs) were determined and disperse-phase distribution of them was established. The total content of light PAHs (naphthalene, acenaphthylene, acenaphthene, fluorine, phenanthrene, anthracene, fluoranthene, pyrene, benz(a)anthracene, chrysene) ranged between 5.5 and 287.4 ng/dm³. Naphthalene, phenanthrene, fluoranthene prevailed in natural water of Dnieper River, their maximal concentrations were, respectively, 194.5, 142.5, 55.7 ng/l. Shares of light PAHs at rough and thin fractions of suspended particulate matter and their water-soluble part were on average 19, 39 and 42 % respectively. It was established, that disperse-phase distribution of individual PAHs depends on the number of aromatic rings in the molecule of the compound: the higher this number the lower water-soluble part of PAH. Only naphthalene exists predominantly in water-soluble state. PAHs with number of aromatic rings 3 or 4 are almost completely associated with suspended particles.

Keywords: natural water, Dnieper River, light PAHs, SPE, HPLC/FD, monitoring, disperse-phase distribution

REFERENCES:

1. Milyukin M.V., Goncharuk V.V. Khimicheskiy monitoring organicheskikh ekotoksikantov v vodnykh sistemakh. Kyiv: Nauk. dumka, 2016. 309 p. [in Russ.]

2. Maystrenko V.N., Khamitov R.Z., Budnikov G.K. Ekologo-analiticheskiy monitoring superekotoksikantov. M.: Khimiya, 1996. 318 p. [in Russ.]

3. Basova E.M., Ivanov V.M. Modern state high pressure liquid chromatography of polycyclic aromatic hydrocarbons. Moscow University Chemistry Bulletin. 2011. V. 52, N 3. P. 163–174. [in Russ.]

4. Milyukin M.V., Skrynnyk M.M., Gorban M.V. Determination of Sorptive Parameters for Organic Toxicants Solubilized by Triton X-100 During their Pre-concentration by Porous Polymer Sorbents from Water Solutions. Methods and objects of chemical analysis. 2015. Vol. 10, No. 4, 189–194. [in Russ.]
DOI: 10.17721/moca.2015.189-194
https://doi.org/10.17721/moca.2015.189-194

5. Linnik P.N. Prichiny ukhudsheniya kachestva vody v Kiyevskom i Kanevskom vodokhranilishchakh. Journal of Water Chemistry and Technology. 2003. V. 25, N 4. P. 384–402. [in Russ.]

6. Liu F., Yang Q., Hu Y. et al. Distribution and transportation of polycyclic aromatic hydrocarbons (PAHs) at the Humen river mouth in the Pearl River delta and their influencing factors. Marine Pollution Bull. 2014. Vol. 84, N 1–2. P. 401–410.
DOI: 10.1016/j.marpolbul.2014.04.045
https://doi.org/10.1016/j.marpolbul.2014.04.045

7. Heemken O.P., Stachel B., Theobald N., Wenclawiak B.W. Temporal variability of organic micropollutants in suspended particulate matter of the River Elbe at Hamburg and the River Mulde at Dessau, Germany. Arch. Environ. Contam. Toxicol. 2000. Vol. 38. P. 11–31.
DOI: 10.1007/s002449910003
https://doi.org/10.1007/s002449910003

8. Feng C., Xia X., Shen Z., Zhou Z. Distribution and sources of polycyclic aromatic hydrocarbons in Wuhan section of the Yangtze River, China. Environ. Monit. Assess. 2007. Vol. 133. P. 447–458.
DOI: 10.1007/s10661-006-9599-5
https://doi.org/10.1007/s10661-006-9599-5

9. Chizhova T.L., Koudryashova Yu.V., Prokuda N.A., Tishchenko P.Ya. Distribution of polycyclic aromatic hydrocarbons in water, suspended matter and bottom deposits in the estuaries of the Peter the Great Bay.Vestnik of the Far East Branch of the Russian Academy of Sciences. 2013. V. 6. P. 149–155. [in Russ.]

10. Guo W., He M., Yang Z. et al. Distribution of polycyclic aromatic hydrocarbons in water, suspended particulate matter and sediment from Daliao River watershed, China. Chemosphere. 2007. Vol. 68. P. 93–104.
DOI: 10.1016/j.chemosphere.2006.12.072
https://doi.org/10.1016/j.chemosphere.2006.12.072

11. Luo X., Chen S., Mai B. et al. Polycyclic aromatic hydrocarbons in suspended particulate matter and sediments from the Pearl River Estuary and adjacent coastal areas, China. Environmental Pollution. 2006. Vol. 139. P. 9–20.
DOI: 10.1016/j.envpol.2005.05.001
https://doi.org/10.1016/j.envpol.2005.05.001

12. Maioli O.L.G., Rodrigues K.C., Knoppers B.A., Azevedo D.A. Distribution and sources of aliphatic and polycyclic aromatic hydrocarbons in suspended particulate matter in water from two Brazilian estuarine systems. Continental Shelf Res. 2011. Vol. 31. P. 1116–1127.
DOI: 10.1016/j.csr.2011.04.004
https://doi.org/10.1016/j.csr.2011.04.004

13. Shi Z., Tao S., Pan B. et al. Contamination of rivers in Tianjin, China by polycyclic aromatic hydrocarbons. Environmental Pollution.2005. Vol. 134. P. 97–111.
DOI: 10.1016/j.envpol.2004.07.014
https://doi.org/10.1016/j.envpol.2004.07.014

14. Maldonado C., Bayona J.M., Bodineau L. Sources, distribution and water column processes of aliphatic and polycyclic aromatic hydrocarbons in the Northwestern Black Sea water. Environmental Science and Technology. 1999. Vol. 31, N 16. P. 2693–2702.
DOI: 10.1021/es9811647
https://doi.org/10.1021/es9811647

15. Lim L., Wurl O., Karuppiah S., Obbard J.P. Atmospheric wet deposition of PAHs to the sea-surface microlayer. Marine Pollution Bull. 2007. Vol. 54. P. 1212–1219.
DOI: 10.1016/j.marpolbul.2007.03.023
https://doi.org/10.1016/j.marpolbul.2007.03.023

16. Qiao M., Huang S., Wang Z. Partitioning characteristics of PAHs between sediment and water in a shallow lake. J. Soils and Sediments.2008. Vol. 8, N 2. P. 69–73.
DOI: 10.1065/jss2008.03.279
https://doi.org/10.1065/jss2008.03.279

17. Qin N., He W., Kong X. et al. Distribution, partitioning and sources of polycyclic aromatic hydrocarbons in the water-SPM-sediment system of Lake Chaohu, China. Science of the Total Environment. 2014. Vol. 496. P. 414–423.
DOI: 10.1016/j.scitotenv.2014.07.045
https://doi.org/10.1016/j.scitotenv.2014.07.045

18. Qi W., Qu J., Liu H. et al. Partitioning and sources of PAHs in wastewater receiving streams of Tianjin, China. Environ. Monit. Assess. 2012. Vol. 184. P. 1847–1855.
DOI: 10.1007/s10661-011-2083-x
https://doi.org/10.1007/s10661-011-2083-x

19. Milyukin M.V., Gorban M.V. Monitoring and Disperse-phase Distribution of Organochlorine Pesticides in Natural Water. Methods and objects of chemical analysis. 2016. Vol. 11, N 1. 25–30. [in Russ.] DOI: 10.17721/moca.2016.25-30
DOI: 10.17721/moca.2016.25-30
https://doi.org/10.17721/moca.2016.25-30

20. Milyukin M.V., Gorban M.V., Skrynnyk M.M. Monitoring and Disperse-phase Distribution of Polychlorinated Biphenyls in Natural Water. Methods and objects of chemical analysis. 2016. Vol. 11, N 2. 81-87. [in Russ.] DOI: 10.17721/moca.2016.99-105
DOI: 10.17721/moca.2016.99-105
https://doi.org/10.17721/moca.2016.99-105

21. Eastcott L., Shiu W.Y., Mackay D. Environmentally relevant physical-chemical properties of hydrocarbons: a review of data and development of simple correlations. Oil and Chemical Pollution. 1988. Vol. 4. P. 191–216.
DOI: 10.1016/S0269-8579(88)80020-0
https://doi.org/10.1016/S0269-8579(88)80020-0

22. De Maagd P.G.J., ten Hulscher D.T.E.M., van den Heuvel H. et al. Physicochemical properties of polycyclic aromatic hydrocarbons: aqueous solubilities, n-octanol/water partition coefficients, and Henry's law constants. Environ. Toxicol. and Chem. 1998. Vol. 17, N 2. P. 251–257.

23. Lei Y.D., Chankalal R., Chan A., Wania F. Supercooled liquid vapour pressures of the polycyclic aromatic hydrocarbons. J. Chem. Eng. Data. 2002. Vol. 47. P. 801–806.
DOI:10.1021/je0155148
https://doi.org/10.1021/je0155148

24. Pavlenko L.F., Skrypnik G.V., Klenkin A.A., Korpakova I.G. Zagryazneniye Azovskogo morya poliaromaticheskimi uglevodorodami. Problems of Fisheries. 2008. V. 9, N 4. P. 861–869. [in Russ.]

25. Khalikov I.S. The contents of PAHs in bottom sediments of the Baikal lake in the region of the Selenga shallow waters. Science Almanac. 2016. V. 15, N 1–2. P. 447–451. [in Russ.]